Crystallographic insight-guided nanoarchitectonics and conductivity modulation of an n-type organic semiconductor through peptide conjugation.

نویسندگان

  • M Pandeeswar
  • Harshavardhan Khare
  • Suryanarayanarao Ramakumar
  • T Govindaraju
چکیده

Crystallographic insight-guided nanoarchitectonics of peptide-conjugated naphthalene diimide (NDI) is described. In a bio-inspired approach, non-proteinogenic α-amino isobutyric acid (Aib)- and alanine (Ala)-derived peptides orchestrated the 1D achiral and 2D chiral molecular ordering of NDI, respectively, which resulted in modulation of nanoscale morphology, chiroptical and conductivity properties.

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عنوان ژورنال:
  • Chemical communications

دوره 51 39  شماره 

صفحات  -

تاریخ انتشار 2015